Here is some online documentation sites:
http://www.cs.dal.ca/splus/contents.html
http://yates.coph.usf.edu/~yiliang/sys/splus.html
http://www.maths.lancs.ac.uk:2080/~maa017/Splus/Intro/intro.html
The very long postscript files that were written before the Springer book of Venables and Ripleys are available at : http://www.math.montana.edu/stat/tutorials/Splus.html
A short handout that explains clearly how to start using Splus: http://www.ms.washington.edu/help/software/splus.html
The most colorful page on Splus I found: http://boserup.qal.berkeley.edu/~carlm/213/Week1/